Probably. If not, then maybe from Spider-Man and His Amazing Friends. Cyke and the rest of the X-Men show up in 2 episodes I believe.
Confirm that the first gif is PRYDE OF THE X-MEN.
Also Cyke and the X-Men have more than 2 appearances in SPIDER-MAN AND HIS AMAZING FRIENDS if you include the less substantial appearance episodes.
Protected by the Comics Code Authority YES Capes. YES Masks. YES Secret Identities.