Hmm...Ideally, since Superman should have a Super powered brain - I'll say yes or, at least the potential is more than there, and with out going to the dark-side. Let's say that Superman's mind works like a quantum computer, then deduction can be accomplished with pure scientific logic of a mathematical formula.
Superman's mind Programming would include any physical and mental makeup like knowing someone's; character, temperament, capabilities, habits surroundings etc... These combinations and, or permutations of variables(depending if the order is assumed) to determine "the method to one's madness".
These factors would be processed internally allowing Superman to make the appropriate algorithm calculation in his head. So, Superman could very well have a more than a good idea, if not, plot exactly - the individuals next course(s) of action.