So on The Heroes side we have.

Spider-man, Quake, Iron Man (in his Civil War Armour), Black Panther, Ghost Rider and War Machine. All are their MCU version naturaly.
y
For the Sinister Six we have.

Green Goblin (Raimi version), Dock Ock (Raimi version), The Lizard (Amazing Spider-man), Vulture (MCU version), Sandman (Raimi version) and Rhino (ASM2 version).

Which team takes it?