My rankings for all movie villains would be....
Molina Ock > Into the Spiderverse Kingpin > Gyllenhaal Mysterio > Spiderverse Lady Ock > Keaton Vulture > Spiderverse Prowler > DaFoe Goblin > SM 3 Sandman > ...... and then a huge drop off..... Franco Harry Goblin > TASM Lizard > TASM 2 Electro > DeHaan Harry Goblin > and the ultimate shit villain Topher Grace Venom *ugh*
Not going to count burglars (from either SM or TASM franchises), Mac Gargan from Homecoming, Shocker(s) from Homecoming, Rhino from TASM 2, Elementals, as they are all too minor to be included imo.