Outside the Spider-related characters, what are Spider-Man's notable superhero friendships?

Some that come to mind:
  • The Fantastic Four, especially Johnny Storm. He's always been the fifth Beatle to them.
  • Daredevil, probably the biggest Dynamic Duo in Marvel (that we rarely get to see outside comics sadly).
  • As far as X-Men goes, there's Iceman, Beast, Nate Grey, Firestar, and as of the '00s, Wolverine.
  • Captain America, despite what the MCU would have you believe it was Cap and not Iron Man who he was closest to on the Avengers.

Who else is of note?