Originally Posted by
Dermie
At least this time around the relationship is at least getting some exploration and panel time. When they first put Carol and Rhodey together, it was entirely out of the blue (the relationship had developed during a time jump between volumes), it required dropping the love interest that the previous volume had spent time building up...and then they immediately launched Carol into space for an extended period, so she had Rhodey were doing the long distance thing and not interacting at all for most of the run. It was bizarre.
Although it has yet to get much in-depth development, the Carol/Rhodey pairing is actually Carol's first successful ongoing romance on-panel since she became Ms. Marvel! Her love life has been a royal mess throughout her publication history.
She was introduced as a love interest for Mar-Vell, but that was dropped when they decided to spin her off as a superhero herself.
The original MS. MARVEL run gave her Mike Barnett but he was more of a friend-with-benefits than an actual boyfriend (partly because Claremont was at times a bit inconsistent about how intimate they were), but ultimately Barnett wanted them to become a more serious couple and Carol just didn't feel that way about him--and then he got murdered by Mystique.
Frank Gianelli was also introduced in that run, but was more of a friend than a love interest at that point (although they did share one kiss). DeConnick brought him back in Carol's first CAPTAIN MARVEL run and set him up as a love interest for Carol...but just as the relationship seemed about to blossom, it was tossed aside off-panel between volumes.
During her original AVENGERS stint Carol had sexual tension and flirtation with Wonder Man, but it didn't go anywhere at that point. She also had some playful flirtation with Captain America and Tony Stark, but it wasn't anything serious.
Then came her time as Binary, and she had no known love life during that period.
When she rejoined the Avengers in Busiek's run he had the Vision ask her out and they casually dated for a short time--but that was more of a friendship than a romance. There was also the Scarlet Centurion as a tragic love interest during the Kang War storyline. He and Carol might have had a good romance--but due to the fact that he looked exactly like the Marcus Immortus who kidnapped and raped her, she couldn't bring herself to ever trust him or her attraction to him.
Brian Reed's MS. MARVEL run implied an off-panel fling between Carol and Johnny Storm in the first issue of his run (Carol made a comment about avoiding the FF after an embarrassing weekend in Vegas with Johnny), but it was just a throwaway line that never got followed up on at all. He gave Carol a love triangle by bringing back the Wonder Man sexual tension and introducing a new civilian love interest named William Wagner. Bendis picked up on the Carol/Simon thing in his MIGHTY AVENGERS run--but started writing them as an actual couple while Carol's solo book still had them in a will they/won't they dynamic since she was torn between the two suitors. Both of those relationships were abruptly dropped around the time of "Secret Invasion"--William was killed off, and Carol slept with Wonder Man to distract herself from her emotional issues at the time...and then apparently broke up with him since he was not seen again for the rest of the series. There has never been any on-panel resolution to their fling.
Presumably both of those relationships were dumped so summarily because Reed wanted to introduce a Carol/Spidey flirtation. That ended up going nowhere--and mainly seemed to be an excuse for Reed to have Spider-Man guest star a lot.
And that's it until Carol became Captain Marvel and ended up with Rhodey. So yeah--prior to Rhodey, Carol's on-panel love life has mainly been false starts and brief flings.