Wouldn't that be kinda redundant? Because instead of going through the effort of making Spidey's web invisible to contain someone, Sue could just use her force fields to contain the enemy herself, and considering her force fields completely outclass his webs in power, she'd be way more effective at containing than him, and combining both, if someone is strong enough to break her force fields, I don't she the web doing much to help.
Though I guess that could work if Sue was busy with something else while he goes contain some enemy while she's busy, but that's kind of a specific situation that shouldn't happen too often.
The thing Spidey would offer the most for the team is how he's a jack of all trades with his power set, since every other members "specializes" in something with their power and skills, Spidey is more flexible, though with a team like F4, I don't know how useful that'd be.
Anyways, I guess some combinations of Spidey's webs with Reed's powers could work, combining them to web some hard to reach place, but it's kind of hard to come across a situation like that, and I don't even know how to use that without just giving Reed a web shooter, so yeah, it's complicated lol.