Cyber, Maverick, Doctor Cornelius, Ogun, Romulus, Daken, Lady Viper, Dog, etc.
He just has the same problem like most solo heroes where he has one-shot villains.
There is the Silver Samurai too. Althought i'm pretty sure that Maverick wasn't a villain.
"Wow. You made Spider-Man sad, congratulations. I stabbed The Hulk last week"
Wolverine, Venom Annual # 1 (2018)
Nobody does it better by Jeff Loveness