Trek the Xybrian (the same species as the TimeForce Green Ranger), the "original" Psycho Ranger (in the comics continuity), takes on the MCU versions of Captain America and the Winter Soldier.
Round I) Psycho Green vs. MCU Captain America.
Round II) Psycho Green vs. MCU Winter Soldier.
Round III) Psycho Green vs. both Captain America and The Winter Soldier.