"Wow. You made Spider-Man sad, congratulations. I stabbed The Hulk last week"
Wolverine, Venom Annual # 1 (2018)
Nobody does it better by Jeff Loveness
"I am Thou, Thou Art I"
Persona
Yeah, in that I agree. Natasha is completely incompatible with Peter and his personality. I do like that she seems to have a healthy amount of respect for him, but I wouldn't see them as a couple in a million years. Nat is way too grey for him and she operates on a different level.
The only thing that's incompatible is Deadpool/Wolverine and Spider-Man. Yet their team-up series works. The same could be done with Spider-Man and Black Widow. The only way that Natasha's relationship with would work is her direct ties to his parents. Peter could be very useful towards Natasha's solo missions by developing tech equipment for her...