Yes, it came out this week. Your comic shop should be able to order it or you can get it at Amazon. I passed on this because I have all the stories in other TPBs or the single issues.
I don't think it had any bonus features.It has some strange omissions. The description:
COLLECTING: Fantastic Four (1961) 5-6, 39-40, 246-247, 258, 278-279, 350, 352; Amazing Spider-Man (1963) 5; Marvel Super-Heroes (1967) 20; Giant-Size Super-Villain Team-Up (1975) 1-2; Super-Villain Team-Up (1975) 13-14; Champions (1975) 16; Amazing Spider-Man Annual (1964) 14; Uncanny X-Men (1981) 145-147; Iron Man (1968) 149-150; Marvel Super Heroes Secret Wars (1984) 10-12; Marvel Graphic Novel (1982): Emperor Doom, Doctor Strange and Doctor Doom - Triumph and Torment; Fantastic Four (1998) 67-70, 500; Fantastic Four Special (2005) 1; Books of Doom (2005) 1-6; material from Fantastic Four (1961) 236, 358; Fantastic Four Annual (1963) 2; Astonishing Tales (1970) 1-3, 6-8; Marvel Double-Shot (2003) 2
Notice in the Lee/Kirby Fantastic Four it doesn't have the arc where he steals the Power Cosmic from the Silver Surfer. There are only 2 issues of Super-Villain Team-Up. Giant-Sized Team up #1 features reprints of the Sub-Mariner #20 and Marvel Superheroes #20. Issue #2 was an original story with Doom and Namor and some rebellious androids. They are skipping over Astonishing Tales 4 and 5. Issue 4 is a goofy little story where Doom takes a vacation on the French Riveria and #5 is when the Red Skull briefly takes over Latveria. I can understand why they don't include Cantwell's series or Infamous Iron Man...maybe because they are too recent I guess. It could be the skipped on the entire SVTU run since there TPB is fairly recent.