Hank Scorpio was Homers boss in the episode You Only Move Twice. Season 8 Episode 2.
Hank was a James Bond Level villain that wanted to take over the world. In fact Homer tackles A James Bond type agent and Hank's men shoot him.
At the end of the episode we see a newspaper headline :Super Villain Seizes East Coast. And he gives Homer the Buffalo Bills Football team as a gift.