Time for a little fly in the ointment.
We'll put this as the New Hampshire team because, really, who's going to check that much on New Hampshire?
The Wizard
Mad Thinker
Blackbox (Formerly Comcast)
Chameleon
Trapster
Shocker
Basically the Wizard and Mad Thinker are going to pull off Zemo's old Thunderbolts trick (because who would ever expect that trick to work again?). As a legitimate superhero team, they're going to be able to access the database on other superhuman teams.
Naturally, they're not going to use their normal villain names.
Wizard: Egotistical enough to be able to play the Team Leader. Belives himself to be the real brains behind the operation.
Mad Thinker: Believes HIMSELF to be the real leader.
Blackbox: As a technological equivalent of a telepath, he's vital to the plans, but believes the organization to be a equal partnership.
Chameleon: The one that really has to deal with pulling off the disguise part of the plan.
Shocker and Trapster: The muscle of the team and the two that were brought in form when you actually need the "super heroes" to actually fight people.