Nope. Storm has never shown any interest into either administration or teaching. She wants to be a team leader and heroine. It seems as if she wanted to be headmistress only to be the leader.
What they should do is to make Nightcrawler the new headmaster, maybe bring Banshee, if they can fix him, or even Kitty Pryde, or hell, even Emma Frost, to be teachers. And let Storm lead the field team. There is no reason the headmaster and the field team leader should belong to the same hierarchy, they should be equals and have authority over their own domain without the intrusion of the other.