Slott has characters that up until him never got exposure to the stories and having them do something useful. He put aunt may as sort of a consulant manager to peter and made robbie the coolest character in the book after peter himself. Character wise, everyone is pretty much at their badic and fundamental characteristics and Peter is acting like he loving being a hero and putting others before his own self as a company policy.
Peter to me is Superman for the cool kids, he shines out for the coomon man and sets the example for pure humanitarian goodwill so he can provide the best way to live life and do the right thing. But he's not a saint like cap or xaviet, hes a guy that like anyone else likes to try new things and use his life as a superhuman to get ahead in life and Peter got to get something outside his control and is actually wanting to take this opportunity serious with a new chance to make up for his own struggles.
OMD and BND(before secret wars 2) always retold Peter as a enabler to regress himself. Never taking responsibility for himself and being shortsighted, no down to earth realist would shut himself off to self sabotage being a hero and live a functional life like peter would and even before the civil war/omd, he stopped caring about his mission as spiderman and to uncle ben, his dream as a scientist, and making his friends and family let them know safe and keep them noticed. MJ replaced alot of his dynamics with people he could hang out and depend including black cat but it still made Peter more less of a main character who is supposed to get stability and grow.
Peter got to secluded in being Peter Parker, and not getting Spider-Man enough to make a balance a priority. Spiderman is Peter Parker and as Spidetman, his core values come out and mean something precious about his character. IMO, its Spidey who made the marriage something, and it's why he and mj love each other or used to because peter could be the person mj could never open up to since spiderman saved peter and spiderman voices his actions right down to his uncle and down being the average joe who cant get by. I think it wasn't being Spider-Man that makes peter fail at life and lose his marriage, it's because he rather be nothing more than Peter Parker and not understand why that isn't all he is. As Spider-Man, he can get his point across and make a difference as Peter Parker he is using Spidey as a disguise to show case how he is still himself who feels he can have his cake and eat it to. This is what screwed him up, peter puts himself as the end all be all priority to do everything without thinking of the consequences that brings spiderman along for the ride, he treats two problems as one choice. A choice that is a risk of danger of others safety without caution
If Peter is gonna stop kingpin and make sure hes behind bars not web him up without a care for the locals just so he can call it a night and go home, he should know about how that would end up if he doesn't want fisk to find out where he lives and how willing hes gonna go to make parker miserable. Peter should have money to make Spider-Man able to be ready for any threat to him, the people he saves or his loved ones.
Being Spidey is the ultimate sacrifice and choice. It won't solve all his problems but it will get him to be more direct in actual success and growing up. And CEO Spidey is the awswer to the question, what if Peter started taking being Spider-Man seriously in order to become someone he can be proud of and make up for all his friends and families that payed for his indecisiveness and failures.