I feel like I must’ve seen him in something before this but my earliest memories of Spider-Man are picking up a graphic novel in 91/92 when I was 4 or 5 years old which involved Peter and Mary Jane going to Paris (and Disney Land) for some function, with Black Fox and Prowler as the villains stealing something - I am sure someone would know the issues involved. But I assume it got me very used to Peter and MJ being married very quickly. I probably wasn’t a serious fan of his until both the first Sam Rami film and the original Ultimate Spider-Man run which I picked up the first six volumes of. Over here in the UK I don’t remember the TAS Spider-Man ever being shown, the BBC had Action Hour instead with Iron Man, Hulk and the Fantastic Four.